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Nihei et al

The reaction was then applied to an unprotected hexapeptide example, with thermal initiation providing no desired product, whilst photochemical conditions gave over 90% conversion via use of DPAP in NMP, with 5 equivalents of 48a

The reciprocal experiment to specifically cleave K29 linkages was technically challenging at this stage because K29/K33-linkage-specific TRABID can also cleave other linkages such as K63 linkage in vitro 34

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