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Both nicotine and nicotine-PLGA nanoparticles normalized the levels of these biomarkers, but nanotization of nicotine improved its bioavailability and efficacy in reducing the indicators of oxidative stress and apoptosis (Tiwari et al., 2013)

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"Results showed a significant linear increase in caffeine sputum levels across 3 weeks post cessation for those who quit smoking and continued using caffeine

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Whereas to smoke pipe tobacco you will need a pipe and a pipe lighter