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The C5 domain of nocardicin NRPS (NocB) not only fulfills its canonical function by forming the corresponding amide bond in the growing peptide chain, but also mediates cyclization of the beta lactam ring 29

Its relevance here stems from a clinical reality: autoimmune thyroid disease primarily Hashimoto's affects women at seven to ten times the rate of men, and is a leading cause of hypothyroidism, fatigue, weight gain, and menstrual irregularity in women aged 3060

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